The rise in the energy demand, the need to decrease the use of fossil fuels, expanding investments in renewable energy and boosting the electric vehicle market, opens the door for new technologies in clean energy accumulators. Lithium-ion batteries are the most advanced technology in the market, but have safety concerns due to the flammability of the electrolyte, which opens the door for innovations. One of these innovations is the solid-state batteries (SSB), which, by using solid electrolytes, do not have the flammable risk, bringing safety to users while reaching similar energy and power densities. This work presents a review about SSB, based on qualitative and exploratory research, using the Web of Science (WoS) platform. Keywords used to gather information from the database were “solid state batteries” and “electrolytes”. Only publications from 2018 to 2023 were selected. The main research focus is to solve the challenges posed by the different physical-chemical phenomena of the SSB. This work focuses on the general comprehension of the SSB batteries, what are the factors that can affect it and the main solutions presented in the literature the last five years.